Preheat oven to 400°F. Line a large, rimmed baking sheet with a silicone baking mat.
Add pork chops to baking sheet. Drizzle with olive oil, approximately 2 tablespoons across all 6 pork chops.
Combine paprika, onion powder, garlic powder, and 1 tsp Italian seasoning in a large mixing bowl. Rub the mixture on both sides of the pork chops and return to the baking sheet. Season with salt and pepper to taste.
Add broccoli to the same bowl and drizzle with remaining olive oil. Add minced garlic and remainder of Italian seasoning to the bowl. Toss to fully coat the broccoli, and season with salt and pepper to taste.
Place broccoli on baking sheet around the pork chops in a single layer. Roast baking sheet in the oven for 23-28 minutes. During the baking process, turn the pork chops once and stir the broccoli once. Baking is done when the pork chops are cooked through (test with a meat thermometer) and the broccoli is browned.
When the baking is done, remove the pan from the oven. Transfer broccoli and pork chops to a serving platter and allow the pork chops to rest for 5-10 minutes. After 5-10 minutes, serve and enjoy!
Always cook meat to temperature, not by time.The broccoli should be spread out in a single layer without crowding. If necessary, use a three-quarter sized sheet pan.